Magnetic properties of DyF3 micro- and nanoparticles
Abstract
The AC/DC magnetic susceptibility and heat capacity of microsized and nanosized DyF3 particles were measured. These measurements were used to estimate the influence of the size of DyF3 particles on their magnetic properties. Dipolar ferromagnetic transition was observed in susceptibility measurements for DyF3 microparticles at TC = 2.54 K, whereas DyF3 nanosized particles remain paramagnetic down to the lowest achieved temperature of 1.8 K. This peculiar behaviour might indicate the change of magnetic properties due to crossover from macro to nanoscale physics.
Supporting agencies: The work supported by the Russian Foundation for Basic Research (Project No.16-32-60155 mol_a_dk).
About the Authors
E. M. Alakshin
Kazan Federal University; Institute of Perspective Research, TAS
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008; L. Bulachnaya 36a, Kazan 420111
E. I. Kondratyeva
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
D. S. Nuzhina
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
M. F. Iakovleva
Kazan Federal University; Leibniz Institute for Solid State and Materials Research, IFW Dresden
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
D-01171 Dresden, Germany
I. F. Gilmutdinov
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
V. V. Kuzmin
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
K. R. Safiullin
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
A. G. Kiiamov
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
A. V. Klochkov
Kazan Federal University; Institute of Perspective Research, TAS
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
L. Bulachnaya 36a, Kazan 420111
M. S. Tagirov
Kazan Federal University; Institute of Perspective Research, TAS
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
L. Bulachnaya 36a, Kazan 420111
References
1. Chatterjee D.K., Rufaihah A.J., Zhang Y. Biomaterials 29, 937 (2008)
2. Wang F., Liu X., Chem. Soc. Rev. 38, 976 (2009)
3. Kong D.Y., Wang Z.L., Lin C.K., Quan Z.W., Li Y.Y., Li C.X. Lin J., Nanotechnology 18, 075601 (2007)
4. Wang F., Zhang Y., Fan X., Wang M. Nanotechnology 17, 1527 (2006)
5. Ansari A.A., Singh N., Singh S.P. J. Nanopart. Res. 10, 703 (2008)
6. Dekker R., Klunder D.J.W., Borreman A., Diemeer M.B.J., Wörhoff K., Driessen A., Stouwdam J.W., Van Veggel F.C.J.M. Appl. Phys. Lett. 85, 6104 (2004)
7. Jüstel T., Nikol H., Ronda C. Angew. Chem. Int. Ed. 37, 3084 (1998)
8. Pudovkin M.S., Morozov O.A., Pavlov V.V., Korableva S.L., Lukinova E.V., Osin Y.N., Evtugyn V.G., Safiullin R.A., Semashko V.V. J. Nanomater. 2017, 3108586 (2017)
9. Norek M., Peters J.A. Prog. Nucl. Magn. Reson. Spectrosc. 59, 64 (2011)
10. Zheng X., Wang Y., Sun L., Chen N., Li L., Shi S., Malaisamy S., Yan C. Nano Res. 9, 1135 (2016)
11. Ma L., Chen W.-X., Zheng Y.-F., Zhao J., Xu Z. Mater. Lett. 61, 2765 (2007)
12. Tagirov M.S., Alakshin E.M., Gazizulin R.R., Egorov A.V., Klochkov A.V., Korableva S.L., Kuzmin V.V., Nizamutdinov A.S, Kono K., Nakao A., Gubaidullin A.T. J. Low Temp. Phys. 162, 645 (2011)
13. Alakshin E.M., Gabidullin B.M., Gubaidullin A.T., Klochkov A.V., Korableva S.L., Neklyudova M.A., Sabitova A.M., Tagirov M.S. arXiv:1104.0208 (2011)
14. Alakshin E.M., Aleksandrov A.S., Egorov A.V., Klochkov A.V., Korableva S.L., Tagirov M.S. JETP Lett. 94, 240 (2011)
15. Alakshin E.M., Blokhin D.S., Sabitova A.M., Klochkov A.V., Klochkov V.V., Kono K., Korableva S.L., Tagirov M.S. JETP Letters. 96, 181 (2012)
16. Alakshin E.M., Gazizulin R.R., Klochkov A.V., Korableva S.L., Kuzmin V.V., Sabitova A.M., Safin T.R., Safiullin K.R., Tagirov M.S. JETP Lett. 97, 579 (2013)
17. Pudovkin M.S., Korableva S.L., Krasheninnicova A.O., Nizamutdinov A.S., Semashko V.V., Zelenihin P.V., Alakshin E.M., Nevzorova T.A. J. Phys.: Conf. Ser. 560, 012011 (2014)
18. Alakshin E.M., Gazizulin R.R., Klochkov A.V., Korableva S.L., Safin T.R., Safiullin K.R., Tagirov M.S. Opt. Spectrosc. 116, 721 (2014)
19. Gazizulina A.M., Alakshin E.M., Baibekov E.I., Gazizulin R.R., Zaharov M.Yu., Klochkov A.V., Korableva S.L., Tagirov M.S. JETP Lett. 99, 149 (2014)
20. Ye X., Chen J., Engel M., Millan J.A., Li W., Qi L., Xing G., Collins J.E., Kagan C.R., Li J., Glotzer S.C., Murray C.B. Nat. Chem. 5, 466 (2013)
21. Alakshin E.M., Klochkov A.V., Kondratyeva E.I., Korableva S.L., Kiiamov A.G., Nuzhina D.S., Stanislavovas A.A., Tagirov M.S., Zakharov M.Yu., Kodjikian S. J. Nanomater. 2016, 7148307 (2016)
22. Bhowmik S., Goraia T., Maitra U. J. Mater. Chem. C 2, 1597 (2014)
23. Li C., Yang J., Yang P., Lian H., Lin J. Chem. Mater. 20, 4317 (2008)
24. Park S.-E., Kim T.-H., Lee S.-R., Namkung S., Jang T.S. J. Appl. Phys. 111, 07A707 (2012)
25. Cao X.J., Chen L., Guo S., Li X.B., Yi P.P., Yan A.R., Yan G.L. J. Alloys Compd. 63, 315 (2015)
26. Sawatzki S., Dirba I., Schultz L., Gutfleisch O. J. Appl. Phys. 114, 133902 (2013)
27. Sueptitz R., Sawatzki S., Moore M., Uhlemann M. Mater. Corros. 66, 152 (2015)
28. Chen D., Yu Y., Huang P., Wang Y. CrystEngComm 11, 1686 (2009)
29. Savinkov A.V., Korableva S.L., Rodionov A.A., Kurkin I.N., Malkin B.Z., Tagirov M.S., Suzuki H., Matsumoto K., Abe S. J. Phys.: Condens. Matter 20, 485220 (2008)
30. Chang Y.Q., Xu X.Y., Luo X.H., Chen C.P., Yu D.P. J. Cryst. Growth 264, 232 (2004)
31. Rong C., Li D., Nandwana V., Poudyal N., Ding Y., Wang Z.L., Zeng H., Liu J.P. Adv. Mater. 18, 2984 (2006)
32. Alloyeau D., Ricolleau C., Mottet C., Oikawa T., Langlois C., Bouar Y.Le., Braidy N., Loiseau A. Nat. Mater. 8, 940 (2009)
33. Sun L., Searson P.C., Chien C.L. Phys. Rev. B 61, R6463 (2000)
34. Kraus W., Nolze G. J. Appl. Crystallogr. 29, 301 (1996)
35. Zalkin A., Templeton D.H. J. Am. Chem. Soc. 75, 2453 (1953)
36. Balanda M. Acta Phys. Pol. A 124, 964 (2013)
37. Holmes L.M., Hulliger F., Guggenheim H.J., Maita J.P. Phys. Lett. A 50, 163 (1974)
Review
For citations:
Alakshin E.M., Kondratyeva E.I., Nuzhina D.S., Iakovleva M.F., Gilmutdinov I.F., Kuzmin V.V., Safiullin K.R., Kiiamov A.G., Klochkov A.V., Tagirov M.S. Magnetic properties of DyF3 micro- and nanoparticles. Magnetic Resonance in Solids. 2017;19(2):17204 (5 pp.).
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