Size-dependent concentration of N0 paramagnetic centres in HPHT nanodiamonds
Abstract
Size-calibrated commercial nanodiamonds synthesized by high-pressure high-temperature (HPHT) technique were studied by high-frequency W- and conventional X-band electron paramagnetic resonance (EPR) spectroscopy. The numbers of spins in the studied samples were estimated. The core-shell model of the HPHT nanodiamonds was proposed to explain the observed dependence of the concentration of the N0 paramagnetic centers. Two other observed paramagnetic centers are attributed to the two types of structures in the nanodiamond shell.
Supporting agencies: This work was partially funded by the subsidy allocated to Kazan Federal University for the project part of the state assignment in the sphere of scientific activities.
About the Authors
B. V. Yavkin
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
G. V. Mamin
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
M. R. Gafurov
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
S. B. Orlinskii
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
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Review
For citations:
Yavkin B.V., Mamin G.V., Gafurov M.R., Orlinskii S.B. Size-dependent concentration of N0 paramagnetic centres in HPHT nanodiamonds. Magnetic Resonance in Solids. 2015;17(1):15101 (7 pp.).
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