Versatile coordination sphere dynamics in o-semiquinonato pincer nickel complexes: an EPR study and mechanistic aspects
Abstract
o-Semiquinonato pincer nickel complexes demonstrate different kinds of coordination sphere dynamics depending from the nature of the phosphorus substituents, the rigindess of the linker in the pincer fragment and the nature of the o-semiquinone.
Supporting agencies: This work was supported by Russian President (grants NSh-1113.2012.3 and MK-474.2011.3), Russian Foundation for Basic Research (grants 10-03-00788-а and 12-03-31087-mol) and FSP “Scientific and scientific-pedagogical cadres of innovation Russia” for 2009-2013 years (GK-P839 from 25.05.2010).
About the Authors
K. A. Kozhanov
G.A. Razuvaev institute of organometallic chemistry of RAS
Russian Federation
Russian Federation
Tropinina, 49, Nizhniy Novgorod, GSP 445, 603950
M. R. Bubnov
G.A. Razuvaev institute of organometallic chemistry of RAS
Russian Federation
Russian Federation
Tropinina, 49, Nizhniy Novgorod, GSP 445, 603950
V. K. Cherkasov
G.A. Razuvaev institute of organometallic chemistry of RAS
Russian Federation
Russian Federation
Tropinina, 49, Nizhniy Novgorod, GSP 445, 603950
G. A. Abakumov
G.A. Razuvaev institute of organometallic chemistry of RAS
Russian Federation
Russian Federation
Tropinina, 49, Nizhniy Novgorod, GSP 445, 603950
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Review
For citations:
Kozhanov K.A., Bubnov M.R., Cherkasov V.K., Abakumov G.A. Versatile coordination sphere dynamics in o-semiquinonato pincer nickel complexes: an EPR study and mechanistic aspects. Magnetic Resonance in Solids. 2012;14(2):12205 (5 pp.).
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