An EPR Monitoring of Isomerism and Coordination Sphere Dynamics in Five-Coordinated Pincer Nickel Complexes
Abstract
A number of five-coordinated paramagnetic pincer nickel complexes have been obtained and investigated by X-band EPR spectroscopy. In general, these complexes can exist in solution as a pair of interconverting structure isomers. Activation parameters of this interconversion were estimated for several complexes.
Supporting agencies: The work was supported by Russian Foundation of Basic Research (grants: 06-03-32753-a, 04-03-32413-а, 06-03-32728-a) and Russian President grant supporting scientific schools: 4947.2006.3.
About the Authors
K. A. Kozhanov
G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences
Russian Federation
Russian Federation
603950, Tropinina str, 49, Nizhny Novgorod
M. R. Bubnov
G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences
Russian Federation
Russian Federation
603950, Tropinina str, 49, Nizhny Novgorod
V. K. Cherkasov
G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences
Russian Federation
Russian Federation
603950, Tropinina str, 49, Nizhny Novgorod
G. K. Fukin
G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences
Russian Federation
Russian Federation
603950, Tropinina str, 49, Nizhny Novgorod
N. N. Vavilina
G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences
Russian Federation
Russian Federation
603950, Tropinina str, 49, Nizhny Novgorod
L. Yu. Efremova
G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences
Russian Federation
Russian Federation
603950, Tropinina str, 49, Nizhny Novgorod
G. A. Abakumov
G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences
Russian Federation
Russian Federation
603950, Tropinina str, 49, Nizhny Novgorod
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Review
For citations:
Kozhanov K.A., Bubnov M.R., Cherkasov V.K., Fukin G.K., Vavilina N.N., Efremova L.Yu., Abakumov G.A. An EPR Monitoring of Isomerism and Coordination Sphere Dynamics in Five-Coordinated Pincer Nickel Complexes. Magnetic Resonance in Solids. 2006;8(1):20-23.
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