Synthesis and study of the cerium doped hydroxyapatite powders
https://doi.org/10.26907/mrsej-24103
Abstract
Hydroxyapatite (HAp) is an attractive material for creating biocompatible implants owing to its osteoregenerative properties, elemental and phase similarity to bone tissue. The flexible structure of the material allows the introduction of ionic impurities to improve physicochemical and biological characteristics while maintaining the space symmetry group. Rare earth ions are a new step in improving compounds to create luminescent bioimaging agent for application in diagnostics imaging medicine. Nanosized powder of HAp doped with cerium ions (Ce-HAp) was obtained in order to study the impurity localization and its oxidizing state with conventional and pulsed electron paramagnetic resonance (EPR) at X-band. Undoped and doped HAp powders were synthesized via precipitation technique. It was revealed, that Ce-HAp powders after synthesis and heating exhibit luminescence in visible wavelength range (380 and 420 nm) that confirms the presence of Ce3+ in HAp structure. Heating of Ce-HAp in the air atmosphere results in formation of CeO2 with low intensity of luminescence. EPR spectra of the doped sample confirms the Ce3+ incorporation into HAp structure. The powder-like EPR lineshape for the obtained powders can be simulated with g∥ = 3.47 and g⊥ = 0.51.
Keywords
electron paramagnetic resonance,
electron spin echo,
hydroxyapatite,
rare earth element,
photoluminescence
Supporting agencies: Authors acknowledge the Russian Science Foundation Grant No. 23-23-00640 for financial support of this study.
About the Authors
Y. O. Nikitina
A.A. Baikov Institute of Metallurgy and Materials Science RAS
Russian Federation
Russian Federation
Moscow 119334
N. V. Petrakova
A.A. Baikov Institute of Metallurgy and Materials Science RAS
Russian Federation
Russian Federation
Moscow 119334
E. I. Maksimenko
A.A. Baikov Institute of Metallurgy and Materials Science RAS
Russian Federation
Russian Federation
Moscow 119334
S. V. Chizhevskaya
D. Mendeleyev University of Chemical Technology of Russia
Russian Federation
Russian Federation
Moscow 125480
S. M. Andreev
St. Petersburg State University
Russian Federation
Russian Federation
Peterhof 198504
M. A. Sadovnikova
Kazan Federal University
Russian Federation
Russian Federation
Kazan 420008
F. F. Murzakhanov
Kazan Federal University
Russian Federation
Russian Federation
Kazan 420008
G. V. Mamin
Kazan Federal University
Russian Federation
Russian Federation
Kazan 420008
M. R. Gafurov
Kazan Federal University
Russian Federation
Russian Federation
Kazan 420008
V. S. Komlev
A.A. Baikov Institute of Metallurgy and Materials Science RAS
Russian Federation
Russian Federation
Moscow 119334
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Review
For citations:
Nikitina Y.O., Petrakova N.V., Maksimenko E.I., Chizhevskaya S.V., Andreev S.M., Sadovnikova M.A., Murzakhanov F.F., Mamin G.V., Gafurov M.R., Komlev V.S. Synthesis and study of the cerium doped hydroxyapatite powders. Magnetic Resonance in Solids. 2024;26(1):24103 (11 pp.). https://doi.org/10.26907/mrsej-24103
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