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High-entropyoxideMg 0.2 Co 0.2 Fe 0.2 Ni 0.2 Zn 0.2 O: synthesis,X-ray diraction and Mossbauerstudies

https://doi.org/10.26907/mrsej-24304

Abstract

High-entropy oxide Mg0.2Co0.2Fe0.2Ni0.2Zn0.2O was successfully synthesized. Using X-ray diffraction analysis, it was found that the sample has a single-phase composition with the NaCl-type face-centered cubic structure and the lattice constant of 4.22 Å. The sample was studied using Mössbauer spectroscopy at temperatures from 80 K to 295 K. It was determined that the relative content of divalent and trivalent iron ions in the sample is 67% and 33%, respectively. Based on the temperature dependence of the hyperfine magnetic field on 57Fe nuclei, the magnetic transition temperature was determined to be 201 K.

About the Authors

V. F. Musin
Kazan Federal University
Russian Federation

Kazan420008



A. L. Zinnatullin
Kazan Federal University
Russian Federation

Kazan420008



F. G. Vagizov
Kazan Federal University
Russian Federation

Kazan420008



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Review

For citations:


Musin V.F., Zinnatullin A.L., Vagizov F.G. High-entropyoxideMg 0.2 Co 0.2 Fe 0.2 Ni 0.2 Zn 0.2 O: synthesis,X-ray diraction and Mossbauerstudies. Magnetic Resonance in Solids. 2024;26(3):24304 (6 pp.). https://doi.org/10.26907/mrsej-24304

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