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Two-dimensional normal distribution of zero field splitting parameters for EPR spectra of human serum transferrin

https://doi.org/10.26907/mrsej-25202

Abstract

n approximation of a distribution of zero field splitting (ZFS) parameters by using two-dimensional normal distributions in discrete representation is proposed. The results of modelling the X-band EPR spectra of human serum transferrin are in a good accordance with experiment. For a number of studied EPR spectra, it was found that the desired distribution consists of two components with various rhombicity parameters. The first component is characterized by a relative high degree of correlation between the parameters E and D. For the second component of ZFS, which we associate with iron bound to the C-lobe iron site of human serum transferrin, a high dispersion of the correlation coefficient is observed.

About the Authors

M. I. Ibragimova
Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RAS
Russian Federation

Kazan



A. I. Chushnikov
Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RAS
Russian Federation

Kazan



I. V. Yatsyk
Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RAS
Russian Federation

Kazan



G. G. Gumarov
Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RAS
Russian Federation

Kazan



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Review

For citations:


Ibragimova M.I., Chushnikov A.I., Yatsyk I.V., Gumarov G.G. Two-dimensional normal distribution of zero field splitting parameters for EPR spectra of human serum transferrin. Magnetic Resonance in Solids. 2025;27(2):25202 (11 pp.). https://doi.org/10.26907/mrsej-25202

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