Low-temperature luminescence spectrum of forbidden 4f135d‐4f14 transitions in CaF2:Lu3+ crystal
https://doi.org/10.26907/mrsej-19413
Abstract
The Lu3+ 4f 135d‐4f 14 VUV luminescence in CaF2:Lu3+ crystal at 8 K was studied with a high spectral resolution using synchrotron radiation excitation. Absence of a zero-phonon line in the recorded spectrum was explained and features in the recorded spectrum were reproduced by simulation based on the microscopic model of electron-phonon interaction and the developed theory of non-Condon spectra.
About the Authors
O. V. Solovyev
Kazan Federal University
Russian Federation
Russian Federation
Kremlevskaya 18, Kazan 420008
V. N. Makhov
P.N. Lebedev Physical Institute
Russian Federation
Russian Federation
Leninskiy Prospekt 53, Moscow 119991
H. Stryhanyuk
Helmholtz Centre for Environmental Research ‐ UFZ
Germany
Germany
Department of Isotope Biogeochemistry, 04318 Leipzig
M. Kirm
Institute of Physics, University of Tartu
Estonia
Estonia
W. Ostwald Str. 1, Tartu 50411
References
1. Van Pieterson L., Reid M.F., Wegh R.T., Soverna S., Meijerink A. Phys. Rev. B 65, 045113 (2002)
2. Malkin B.Z., Solovyev O.V., Malishev A.Yu., Saikin S.K. J. Lumin. 125, 175 (2007)
3. Kirm M., Stryganyuk G., Vielhauer S., Zimmerer G., Makhov V.N., Malkin B.Z., Solovyev O.V., Abdulsabirov R.Yu., Korableva S.L. Phys. Rev. B 75, 075111 (2007)
4. Solovyev O.V. Phys. Solid State 52, 728 (2010)
5. Zimmerer G. Radiat. Meas. 42, 859 (2007)
6. Makhov V.N. Phys. Scripta 89, 044010 (2014)
7. Bel'skii A.N., Vasil'ev A.N., Ivanov S.N., Kamenskikh I.A., Kolobanov V.N., Makhov V.N., Spasskii D.A. Crystallogr. Rep. 61, 886 (2016)
8. Makhov V.N., Batygov S.Kh., Dmitruk L.N., Kirm M., Vielhauer S., Stryganyuk G. Phys. Solid State 50, 1625 (2008)
9. Elcombe M.M., Pryor A.W. J. Phys. C 3, 492 (1970)
10. Ignatiev I.V. Fizika Tverdogo Tela 32, 2698 (1990) (in Russian)
11. Malkin B.Z., in Spectroscopy of Solids Containing Rare-Earth Ions, edited by A.A. Kaplyanskii and R.M. Macfarlane, North-Holland, Amsterdam (1987), p. 13
12. Clementi E., Mclean A.D. Phys. Rev. A 133, 419 (1964)
13. Starostin N.V., in Spectroscopy of Crystals, Nauka, Moskva (1975), p. 256 (in Russian)
14. Reid M.F., van Pieterson L., Meijerink A. J. Alloys Compd. 344, 240 (2002)
15. Solovyev O.V., Malkin B.Z. J. Mol. Struct. 838, 176 (2007)
16. Kubo R., Toyodzawa Y. Prog. Theor. Phys. 13, 160 (1955)
17. Malkin B.Z., in Paramagnetic Resonance, Kazan University, Kazan (1968), Vol. 4, p. 3 (in Russian)
18. Sugar J., Kaufman V.J. Opt. Soc. Am. 62, 562 (1972)
19. Solovyev O.V. Magn. Reson. Solids 11, 14 (2009)
20. Pan Z., Duan C.-K., Tanner P.A. Phys. Rev. B 77, 085114 (2008)
21. Solovyev O.V., Yunusov R.Yu. Opt. Spectrosc. 116, 754 (2014)
Review
For citations:
Solovyev O.V., Makhov V.N., Stryhanyuk H., Kirm M. Low-temperature luminescence spectrum of forbidden 4f135d‐4f14 transitions in CaF2:Lu3+ crystal. Magnetic Resonance in Solids. 2019;21(4):19413 (7 pp.). https://doi.org/10.26907/mrsej-19413
Views:
20
Email this article 