Lithium diffusion in a new cathode material Li0.8[Ni0.6Sb0.4]O2 studied by 7Li NMR
Abstract
A rhombohedral layered α-NaFeO2-type compound, Lix[Ni(1+x)/3Sb(2-x)/3]O2 (x=0.8) has been prepared from the sodium analogue by ion exchange at 570 K. In contrast to the stoichiometric composition Li3Ni2SbO6, it shows considerable Li/Ni inversion and no long-range Ni/Sb ordering. The temperature dependence of the 7Li NMR spin-lattice relaxation rate and linewidth data measured at temperature range from 30-450 K show the sharp increase of lithium ions mobility comparing to the stoichiometric compound Li3Ni2SbO6. From the NMR data the activation energy was estimated by different methods.
Supporting agencies: This work was supported by grants 14-03-01122 (I.S. and V.N.), 14-02-00245 (E.Z.) and 14-02-01194 (T.S. and E.V.) from Russian Foundation for Basic Research. Initial XRD characterization of Li0.8Ni0.6Sb0.4O2 was supported by the Grant-in-Aid 00-15 from the International Centre for Diffraction Data.
About the Authors
T. Salikhov
Zavoisky Physical-Technical Institute of RAS
Russian Federation
Russian Federation
Sibirskii trakt 10/7, Kazan 420029
E. Klysheva
Zavoisky Physical-Technical Institute of RAS
Russian Federation
Russian Federation
Sibirskii trakt 10/7, Kazan 420029
E. Zvereva
Faculty of Physics, Moscow State University
Russian Federation
Russian Federation
Leninskie Gory 1-2, Moscow 119991
V. Nalbandyan
Chemistry Faculty, Southern Federal University
Russian Federation
Russian Federation
Sorge 7, Rostov-on-Don 344090
I. Shukaev
Chemistry Faculty, Southern Federal University
Russian Federation
Russian Federation
Sorge 7, Rostov-on-Don 344090
B. Medvedev
Chemistry Faculty, Southern Federal University
Russian Federation
Russian Federation
Sorge 7, Rostov-on-Don 344090
E. Vavilova
Zavoisky Physical-Technical Institute of RAS
Russian Federation
Russian Federation
Sibirskii trakt 10/7, Kazan 420029
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Review
For citations:
Salikhov T., Klysheva E., Zvereva E., Nalbandyan V., Shukaev I., Medvedev B., Vavilova E. Lithium diffusion in a new cathode material Li0.8[Ni0.6Sb0.4]O2 studied by 7Li NMR. Magnetic Resonance in Solids. 2016;18(2):16207 (8 pp.).
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