Analysis of the thermal treatment effects of gadolinium-containing hydroxyapatite by EPR method
https://doi.org/10.26907/mrsej-23303
Abstract
Hydroxyapatite (HAp)-based materials doped with rare earth elements (REE) have shown applications as biomaterials, lighting emitting materials, scintillating materials, in vivo imaging probes, and thermoluminescent dosimeters. Gadolinium-containing calcium phosphates are promising contrast agents for various bioimaging modalities. In this work, hydroxyapatite materials with gadolinium ion impurities with a 0.44 mol.% concentration were obtained by wet chemical precipitation. Samples after chemical synthesis (as-dried) and heat treatment were studied using electron paramagnetic resonance (EPR) spectroscopy in continuous wave and pulsed modes. Analysis of the EPR spectra made it possible to establish the incorporation of Gd 3+ ions in the structure of HAp in two calcium positions with different parameters of the spin Hamiltonian. Heat treatment of samples at a T = 1300°C leads to a significant change in the EPR spectra of Gd 3+ ions with a decrease of the uncontrolled nitrate anion centers (synthesis by-product) concentration
Supporting agencies: Authors acknowledge the Russian Science Foundation Grant No. 23-63-10056 for financial support of this study
About the Authors
A. Yu. Demina
A.A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
Russian Federation
Russian Federation
Moscow 119991
N. V. Petrakova
A.A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
Russian Federation
Russian Federation
Moscow 119991
F. F. Murzakhanov
Kazan Federal University
Russian Federation
Russian Federation
Kazan 420008
G. V. Mamin
Kazan Federal University
Russian Federation
Russian Federation
Kazan 420008
Yu. O. Nikitina
A.A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
Russian Federation
Russian Federation
Moscow 119991
M. A. Sadovnikova
Kazan Federal University
Russian Federation
Russian Federation
Kazan 420008
S. O. Andreev
St.Petersburg State University
Russian Federation
Russian Federation
Peterhof 198504
A. V. Zhukov
D. Mendeleyev University of Chemical Technology
Russian Federation
Russian Federation
Moscow 125480
M. R. Gafurov
Kazan Federal University
Russian Federation
Russian Federation
Kazan 420008
V. S. Komlev
A.A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
Russian Federation
Russian Federation
Moscow 119991
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Review
For citations:
Demina A.Yu., Petrakova N.V., Murzakhanov F.F., Mamin G.V., Nikitina Yu.O., Sadovnikova M.A., Andreev S.O., Zhukov A.V., Gafurov M.R., Komlev V.S. Analysis of the thermal treatment effects of gadolinium-containing hydroxyapatite by EPR method. Magnetic Resonance in Solids. 2023;25(3):23303 (11 pp.). https://doi.org/10.26907/mrsej-23303
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